Introduction
Nanodiamonds are nano-sized particles of diamond. They are gaining prominence in the field of material science due to their unique properties, such as high surface area, excellent thermal conductivity, and superior mechanical strength. When incorporated into polymer matrices, nanodiamonds contribute significantly to the enhancement of the composite’s overall performance. This editorial article imparts findings from recent research articles on the role of nanodiamonds in polymer hybrid composites, focusing on the common types of polymer matrices and fillers used alongside nanodiamonds, the influence of nanodiamonds on composite properties, and the advantages of incorporating nanodiamonds.
Polymer Matrices and Fillers
Among the various polymer matrices explored for use with nanodiamonds, epoxy resin (ER) [1,2] and styrene-butadiene rubber (SBR) [3] are predominant. These polymers are chosen based on their processability with nanodiamonds and the specific properties desired in the final product. ER is known for its excellent adhesive properties and chemical resistance [4], which is frequently used to attain a strong binding matrix for nanodiamonds, which enhances mechanical and thermal properties. Figure 1 shows the chemical structures of (a) ER and (b) SBR.
Figure 1: Chemical structures of (a) ER and (b) SBR.
Fillers such as carbon nanotubes (CNTs) [5], silica [6], and graphene (Gra) [7] are commonly paired with nanodiamonds to leverage synergistic effects that can significantly improve both thermal and mechanical properties. For example, the combination of CNTs and nanodiamonds in an epoxy matrix has been shown to improve not only the glass transition temperature but also the thermal conductivity [5,8], making the composite suitable for applications requiring rapid heat dissipation. Figure 2 displays the chemical structures of (a) CNTs and (b) Gra.
Figure 2: Chemical structures of (a) CNTs and (b) Gra.
Influence of Nanodiamonds on Composite Properties
Incorporating nanodiamonds into polymer composites leads to notable enhancements in mechanical properties such as tensile strength, flexural strength, and hardness [2,9]. A specific study has demonstrated that incorporating nanodiamonds into epoxy composites can increase hardness, tensile strength, and flexural strength by approximately 34.38%, 28.01%, and 21.12%, respectively [10], underscoring the influence of nanodiamonds on reinforcing the structural integrity of composites.
The thermal properties of polymer composites are also significantly enhanced by the incorporation of nanodiamonds. This is attributed to nanodiamonds’ intrinsic high thermal conductivity [3,11], which facilitates the formation of efficient thermal conductive networks within the composite [8]. In applications that require enhanced heat dissipation, such as in electronic and aerospace components [8,11], the improved thermal conductivity provided by nanodiamonds is particularly beneficial.
Advantages of Nanodiamonds in Polymer Hybrid Composites
The superior hardness and mechanical strength of nanodiamonds translate into improved wear resistance and durability for the composite materials [1,2]. This makes nanodiamond-reinforced polymer composites particularly valuable for industrial applications where mechanical strength is crucial.
Nanodiamonds distribute thermal energy effectively throughout the polymer composite, enhancing the composite material’s ability to manage heat [3,9]. This property is essential for applications involving high thermal loads, where maintaining structural integrity at elevated temperatures is critical.
When used in conjunction with other nanoscale materials like CNTs and Gra [12], nanodiamonds help in achieving composite materials with optimized properties. For instance, the hybridization of nanodiamonds with Gra not only improves tensile strength but also significantly boosts fracture toughness [7], a critical factor for materials used in safety-critical applications.
Nanodiamonds adapt well to various polymer matrices and complement primary fillers [6,10], broadening the scope of their application. Nanodiamonds contribute positively to essential sectors, from lightweight aerospace parts that require excellent strength-to-weight ratios to electronic components that benefit from enhanced thermal management.
Conclusion
In summary, nanodiamonds are proving to be a transformative addition to polymer hybrid composites, offering substantial improvements in both mechanical and thermal properties. The ability to synergistically combine nanodiamonds with other fillers opens up new possibilities for the development of advanced composites tailored for specific industrial applications. Continued research into nanodiamond-incorporated polymer composites is expected to enhance their application potential further, making them indispensable in the fields of aerospace, electronics, automotive, and beyond. The growing area of research and expanding applications highlights the significant role nanodiamonds play in developing next-generation composite materials.
References
2. Subhani T, Khaliq A, Farooq U, Khurram AA. Microstructural and Mechanical Profile of Carbon Fiber Epoxy Matrix Composites Containing Nanodiamonds. Microscopy and Microanalysis. 2020 Aug;26(S2):2380-2.
3. Jafarpour E, Shojaei A, Ahmadijokani F. High-performance styrene-butadiene rubber nanocomposites based on carbon nanotube/nanodiamond hybrid with synergistic thermal conduction characteristics and electrically insulating properties. Polymer. 2020 May 20;196:122470.
4. Shamsuri AA, Abdan K, Yusoff MZ, Jamil SN. Impact of ionic liquids on the thermal properties of polymer composites. e-Polymers. 2024 Apr 2;24(1):20240020.
5. Xian Y, Kang Z, Liang X. Effect of nanodiamonds and multi‐walled carbon nanotubes in thermoset hybrid fillers system: Rheology, dynamic mechanical analysis, and thermal stability. Journal of Applied Polymer Science. 2021 Jun 5;138(21):50496.
6. Mohammadi A, Shojaei A, Khasraghi SS. Improvement of nanosilica effects on the performance of mechanically processed styrene-butadiene rubber by rational hybridization with nanodiamond. Diamond and Related Materials. 2022 Dec 1;130:109487.
7. Bisht A, Samant SS, Jaiswal S, Dasgupta K, Lahiri D. Quantifying nanodiamonds assisted exfoliation of graphene and its effect on toughening behaviour of composite structure. Composites Part A: Applied Science and Manufacturing. 2020 May 1;132:105840.
8. Xian Y, Kang Z. Hydrogen bonds leading nanodiamonds performing different thermal conductance enhancement in different MWCNTs epoxy-based nanocomposites. Progress in Organic Coatings. 2020 Mar 1;140:105486.
9. Wang J, Khan M, Tiehu L, Javed E, Hussain A, Zada A, et al. Preparation and structural investigations of the graphite and nanodiamonds dispersed epoxy hybrid composites for enhanced mechanical and thermal properties. Bulletin of Materials Science. 2022 Aug 13;45(3):160.
10. Arun Kumar M, Selvaraj S.K, Kanniyappan S, Karthikeyan B, Chadha U. Effects of Adding Nanodiamonds in Mechanical Properties of Jute and Ramie Fiber Reinforced Epoxy Composites. Polymer. Composites. 2024;45:11872–82.
11. Zhao K, Liu G, Cao W, Su Z, Zhao J, Han J, et al. A combination of nanodiamond and boron nitride for the preparation of polyvinyl alcohol composite film with high thermal conductivity. Polymer. 2020 Oct 7;206:122885.
12. Shamsuri AA, Md. Jamil SN, Yusoff MZ, Abdan K. Polymer Composites Containing Ionic Liquids: A Study of Electrical Conductivity. Electronic Materials. 2024 Sep 26;5(4):189-203.